(4E)-4-Hexen-3-one

Names

[ Name ]:
(4E)-4-Hexen-3-one

[Synonym ]:
4-Hexen-3-one
4-HEXENE-3-ONE
E-4-hexen-3-one
trans-hex-4-en-3-one
(4E)-4-Hexen-3-one
FEMA 3352
hexene-4-one-3
MFCD00010631
trans 4-hexen-3-one
4-Hexen-3-one, (4E)-
4-Hexen-3-one,predominantly trans
(E)-4-hexene-3-one
2-Hexene-4-one
(4E)-Hex-4-en-3-one
(E)-hex-4-ene-3-one
hex-4-en-3-one
2-Hexen-4-one
EINECS 219-681-2

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
138.5±0.0 °C at 760 mmHg

[ Melting Point ]:
-71.05°C (estimate)

[ Molecular Formula ]:
C₆H₁₀O

[ Molecular Weight ]:
98.143

[ Flash Point ]:
34.4±0.0 °C

[ Exact Mass ]:
98.073166

[ PSA ]:
17.07000

[ LogP ]:
1.09

[ Vapour Pressure ]:
6.7±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.420

[ Storage condition ]:
Flammables area

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MP8659900

CHEMICAL NAME :: 2-Hexen-4-one

CAS REGISTRY NUMBER :: 2497-21-4

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C6-H10-O

MOLECULAR WEIGHT :: 98.16

WISWESSER LINE NOTATION :: 2V1U2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 780 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DCTODJ Drug and Chemical Toxicology. (Marcel Dekker, 270 Madison Ave., New York, NY 10016) V.1- 1977/78- Volume(issue)/page/year: 3,249,1980

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
16-26-36/37/39

[ RIDADR ]:
UN 1224

[ WGK Germany ]:
3

[ RTECS ]:
MP8659900

[ Packaging Group ]:
III

[ Hazard Class ]:
3

Precursor & DownStream

Precursor

DownStream

Articles

Kinetic investigation of the OH radical and Cl atom initiated degradation of unsaturated ketones at atmospheric pressure and 298 K.

J. Phys. Chem. A 116(24) , 6033-40, (2012)

Rate coefficients for the reactions of hydroxyl radicals and chlorine atoms with 4-hexen-3-one, 5-hexen-2-one, and 3-penten-2-one have been determined at 298 ± 2 K and atmospheric pressure of air. Rat...

Monitoring the oxidation of edible oils by Fourier transform infrared spectroscopy. Van de Voort FR, et al.

J. Am. Oil Chem. Soc. 71(3) , 243-53, (1994)