di-tert-butyl nitroxide
Names
[ CAS No. ]:
2406-25-9
[ Name ]:
di-tert-butyl nitroxide
[Synonym ]:
N,N-di-tert-butylnitroxide
DI-TERT-BUTYL NITROXYL
ditertiary butyl nitroxide
MFCD00008800
EINECS 219-298-0
DI-T-BUTYL NITROXIDE
di-t-Butylnitroxyl
di-tert-butylnitroxide radical
nitroxide,di-tert-butyl
Dtbn
Chemical & Physical Properties
[ Density]:
0.877g/cm3
[ Boiling Point ]:
74-75ºC34 mm Hg(lit.)
[ Molecular Formula ]:
C8H18NO
[ Molecular Weight ]:
144.23500
[ Flash Point ]:
114 °F
[ Exact Mass ]:
144.13900
[ PSA ]:
3.24000
[ LogP ]:
2.23090
[ Index of Refraction ]:
1.435
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- RA1780000
- CHEMICAL NAME :
- Nitroxide, di-tert-butyl
- CAS REGISTRY NUMBER :
- 2406-25-9
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C8-H18-N-O
- MOLECULAR WEIGHT :
- 144.27
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 505 mg/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - mydriasis (pupillary dilation) Sense Organs and Special Senses (Eye) - lacrimation Sense Organs and Special Senses (Eye) - conjunctive irritation
- REFERENCE :
- JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 141,349,1963
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 53800 ug/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - mydriasis (pupillary dilation) Sense Organs and Special Senses (Eye) - lacrimation Sense Organs and Special Senses (Eye) - conjunctive irritation
- REFERENCE :
- JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 141,349,1963
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H302-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn: Harmful;
[ Risk Phrases ]:
R10;R22;R36/37/38
[ Safety Phrases ]:
S16;S26;S36
[ RIDADR ]:
UN 1993
[ WGK Germany ]:
3
[ RTECS ]:
RA1780000
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
Synthetic Route
Articles
J. Phys. Chem. A 114(21) , 6217-25, (2010)
We present electron spin resonance (ESR) experiments that describe the interaction of beta-cyclodextrin (beta-CD) with spin adducts of three spin traps: 5,5-dimethyl-1-pyrroline N-oxide (DMPO), N-tert...
Stratum corneum intercellular lipid as compared to erythrocyte ghosts: an ESR study of thermotropic behavior and nitroxide reduction. Electron Spin Resonance.Physiol. Chem. Phys. Med. NMR 27(1) , 63-72, (1995)
Intercellular membranes of Stratum Corneum and erythrocyte ghosts were studied through partition of Tempo nitroxide spin label. Stratum Corneum presents a phase transition-monitored by the spin label ...
Guest inclusion in cucurbiturils studied by ESR and DFT: the case of nitroxide radicals and spin adducts of DMPO and MNP.J. Phys. Chem. A 116(33) , 8475-83, (2012)
We present an ESR and DFT study of the interaction of cucurbiturils CB[6], CB[7], and CB[8] with di-tert-butyl nitroxide ((CH(3))(3)C)(2)NO (DTBN) and with spin adducts of 5,5-dimethyl-1-pyrroline-N-o...