2-Chloro-4-fluoroanisole

Names

[ Name ]:
2-Chloro-4-fluoroanisole

[Synonym ]:
2-Chlor-4-fluor-anisol
2-Chloro-4-fluoroanisole
GR CF FO1
Benzene,2-chloro-4-fluoro-1-methoxy
4-fluoro-2-chloroanisole
MFCD00672965
Benzene, 2-chloro-4-fluoro-1-methoxy-
2-Chloro-4-fluoro-1-methoxybenzene
2-chloro-4-fluoro-anisole
2-CHLORO-4-FLUORO-1-METHOXY-BENZENE
2-Chloro-4-fluorophenyl methyl ether

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
191.5±20.0 °C at 760 mmHg

[ Melting Point ]:
197-200ºC

[ Molecular Formula ]:
C₇H₆ClFO

[ Molecular Weight ]:
160.573

[ Flash Point ]:
69.6±21.8 °C

[ Exact Mass ]:
160.009125

[ PSA ]:
9.23000

[ LogP ]:
2.36

[ Vapour Pressure ]:
0.7±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.495

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Cp2Fe(PR2)2PdCl2 (R = i-Pr, t-Bu) complexes as air-stable catalysts for challenging Suzuki coupling reactions.

Org. Lett. 6 , 3731, (2004)

[reaction: see text] The use of Cp(2)Fe(PR(2))(2)PdCl(2) (R = i-Pr and t-Bu) in Suzuki coupling reactions were illustrated using a high throughput screening approach. The di-tbpfPdCl(2) catalyst was s...

Organometallic sandwich compounds in homogeneous catalysis: an overview. Colacot TJ and Hosmane NS.

Z. Anorg. Allg. Chem. 631(13-14) , 2659-2668, (2005)