3-Biphenylamine

Names

[ Name ]:
3-Biphenylamine

[Synonym ]:
MFCD00047846
[1,1'-Biphenyl]-3-amine
3-Aminodiphenyl
biphenyl-3-ylamine
3-amino-1,1'-biphenyl
M-AMINOBIPHENYL
Biphenyl-3-amine
3-Biphenylamine
(1,1'-Biphenyl)-3-amine (9CI)
3-Phenylaniline
m-Phenylaniline

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
341.7±21.0 °C at 760 mmHg

[ Melting Point ]:
28-33ºC

[ Molecular Formula ]:
C₁₂H₁₁N

[ Molecular Weight ]:
169.222

[ Flash Point ]:
177.0±17.4 °C

[ Exact Mass ]:
169.089142

[ PSA ]:
26.02000

[ LogP ]:
2.42

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.619

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DU8900000

CHEMICAL NAME :: 3-Biphenylamine

CAS REGISTRY NUMBER :: 2243-47-2

BEILSTEIN REFERENCE NO. :: 2206824

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C12-H11-N

MOLECULAR WEIGHT :: 169.24

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 10 mg/L

REFERENCE :: ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 5,803,1983

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Hazard Codes ]:
Xn;N

[ Risk Phrases ]:
R22;R36/37/38;R51

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
UN2811

[ RTECS ]:
DU8900000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2921499090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2921499090

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Hemoglobin adducts of aromatic amines: associations with smoking status and type of tobacco.

Proc. Natl. Acad. Sci. U. S. A. 85(24) , 9788-91, (1988)

Hemoglobin adducts of 15 aromatic amines were determined in nonsmokers and smokers of blond- or black-tobacco cigarettes living in Turin, Italy. The subjects were all males age 55 or less and were rep...

Haemoglobin adducts of aromatic amines in people exposed to cigarette smoke.

IARC Sci. Publ. (89) , 133-6, (1988)

In a population-based study in Turin, Italy, smokers of blond tobacco showed 4-aminobiphenyl (4-ABP) adduct levels some three times higher than nonsmoking subjects, and smokers of black tobacco showed...

Elevated blood levels of carcinogens in passive smokers.

Am. J. Public Health 79(10) , 1381-4, (1989)

The hypothesis that involuntary exposure to tobacco smoke--passive smoking--results in greater risk of cancer was assessed by measuring the levels of two known carcinogens in the blood of 57 nonsmoker...