Bromoacetyl chloride
Names
[ CAS No. ]:
22118-09-8
[ Name ]:
Bromoacetyl chloride
[Synonym ]:
Acetyl chloride, 2-bromo-
bromoethanoyl chloride
monobromoacetic acid chloride
MFCD00000724
Acetyl chloride,bromo
Bromoacetyl chloride
EINECS 244-790-7
bromo-acetyl chloride
bromoacethyl chloride
Chemical & Physical Properties
[ Density]:
1.9±0.1 g/cm3
[ Boiling Point ]:
127.0±0.0 °C at 760 mmHg
[ Melting Point ]:
127 - 128 °C
[ Molecular Formula ]:
C2H2BrClO
[ Molecular Weight ]:
157.394
[ Flash Point ]:
26.1±19.8 °C
[ Exact Mass ]:
155.897751
[ PSA ]:
17.07000
[ LogP ]:
1.15
[ Vapour Pressure ]:
11.4±0.2 mmHg at 25°C
[ Index of Refraction ]:
1.487
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314-H335
[ Supplemental HS ]:
Reacts violently with water.
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C:Corrosive;
[ Risk Phrases ]:
R14;R34;R37
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
8
[ HS Code ]:
2915900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2915900090
[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
Articles
Biochem. J. 108(5) , 855-9, (1968)
Papain was irreversibly inhibited by 1,3-dibromoacetone, a reagent designed to react first with the active-site cysteine residue and subsequently with a second nucleophile. The molecular weight of the...
Non-adiabatic effects in the photodissociation of bromoacetyl chloride. Bacchus-Montabonel M-C, et al.Chem. Phys. Lett. 374(3) , 307-13, (2003)
Cycloaddition chemistry of anhydro-4-hydroxy-1, 3-thiazolium hydroxides (thioisomünchnones) for the synthesis of heterocycles. Padwa A, et al.
Synthesis 1994(9) , 993-1004, (1994)