1,4-Benzodioxan-6-amine
Names
[ CAS No. ]:
22013-33-8
[ Name ]:
1,4-Benzodioxan-6-amine
[Synonym ]:
6-Amino-1,4-benzodioxane
3,4-Ethylenedioxyaniline
2,3-Dihydrobenzo[b][1,4]dioxin-6-amine
6-Amino-1,4-benzodioxan
2,3-dihydro-1,4-benzodioxin-6-amin
1,4-Benzodioxan-6-amine
MFCD00006824
EINECS 244-718-4
6-amino-2,3-dihydro-1,4-benzodioxin
Chemical & Physical Properties
[ Density]:
1.231 g/mL at 25 °C(lit.)
[ Boiling Point ]:
116-118°C 3mm
[ Melting Point ]:
29-31 °C(lit.)
[ Molecular Formula ]:
C8H9NO2
[ Molecular Weight ]:
151.16300
[ Flash Point ]:
>230 °F
[ Exact Mass ]:
151.06300
[ PSA ]:
44.48000
[ LogP ]:
1.62120
[ Vapour Pressure ]:
0.0017mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.599(lit.)
[ Water Solubility ]:
insoluble
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R20/21/22;R38
[ Safety Phrases ]:
S26-S37/39-S36/37
[ RIDADR ]:
2810
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
[ HS Code ]:
29329995
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Preparation
Customs
[ HS Code ]: 2932999099
[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
J. Heterocycl. Chem. 47(6) , 1275-1282, (2010)
Novel arylamino alcohols were synthesized and these alcohols were used to prepare 12 novel N-(2-hydroxy-ethyl)-2,3-didehydroazapodophyllotoxins, in one step, by simple reflux in ethanol. Isolated yiel...
2, 3-Dihydrodioxin [2, 3-b] acridin-11 (6H)-one. Karolak-Wojciechowska J, et al.Acta Crystallogr. C 54(11) , 1689-90, (1998)