(Vinylsulfinyl)benzene
Names
[ CAS No. ]:
20451-53-0
[ Name ]:
(Vinylsulfinyl)benzene
[Synonym ]:
(Vinylsulfinyl)benzene
phenyl ethenyl sulphoxide
EINECS 243-831-6
Phenyl Vinyl Sulfoxide
1-vinylsulfinylbenzene
PhS(O)CH=CH2
ethenyl phenyl sulfoxide
(ethenylsulfinyl)benzene
Sulfoxide,phenyl vinyl
VINYL PHENYL SULFOXIDE
MFCD00002086
(+/-)-phenyl-vinyl-sulfoxide
Benzene, (ethenylsulfinyl)-
Phenyl ethenyl sulfoxide
phenyl vinyl sulphoxide
Benzene,(ethenylsulfinyl)
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
317.1±11.0 °C at 760 mmHg
[ Molecular Formula ]:
C8H8OS
[ Molecular Weight ]:
152.214
[ Flash Point ]:
145.6±19.3 °C
[ Exact Mass ]:
152.029587
[ PSA ]:
36.28000
[ LogP ]:
1.02
[ Appearance of Characters ]:
liquid | deeply yellow
[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C
[ Index of Refraction ]:
1.610
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R41
[ Safety Phrases ]:
24/25-39-26
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2930909090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2930909090
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
J. Org. Chem. 62(23) , 8015-8017, (1997)
Vinyl sulfoxides (PhSOCR(1)=CHR(2): R(1) = H, Me, or Ph; R(2) = H or Me) were treated with (dialkylamino)magnesium reagents, generated in situ from the reaction of EtMgBr with secondary amines (R(3)R(...
The formation of bicyclo[n.2.0]alkan-1-ols from the reaction of the lithium enolates of simple ketones and phenyl vinyl sulfoxide.Org. Biomol. Chem. 1(8) , 1347-53, (2003)
The enolates generated from cyclopentanone, cycloheptanone or cyclooctanone and LDA at -78 degrees C in THF react with (+/-)-phenyl vinyl sulfoxide under controlled conditions of temperature, reaction...
The structures of different diastereomers of bicyclo[2.2.1]hept-5-en-2-yl phenyl sulfoxide.Acta Crystallogr. B 45 ( Pt 1) , 93-9, (1989)
Three diastereomers of bicyclo[2.2.1]hept-5-en-2-yl phenyl sulfoxide were prepared by Diels-Alder [4 + 2] cycloadditions between phenyl vinyl sulfoxide and cyclopentadiene. The isomers were separated ...