2-phenylbenzyl bromide
Names
[ CAS No. ]:
19853-09-9
[ Name ]:
2-phenylbenzyl bromide
[Synonym ]:
o-phenylbenzyl bromide
2-biphenylmethyl bromide
2-phenylbenzylbromide
MFCD00075454
2-bromomethylbiphenyl
Chemical & Physical Properties
[ Density]:
1.341g/cm3
[ Boiling Point ]:
374.7ºC at 760mmHg
[ Molecular Formula ]:
C13H11Br
[ Molecular Weight ]:
247.13000
[ Flash Point ]:
169ºC
[ Exact Mass ]:
246.00400
[ LogP ]:
4.24850
[ Vapour Pressure ]:
1.77E-05mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.6280(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS05
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C: Corrosive;
[ Risk Phrases ]:
R34
[ Safety Phrases ]:
26-27-28-36/37/39
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ HS Code ]:
2903999090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2903999090
[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Arch. Pharm. (Weinheim) 348(1) , 55-61, (2015)
The current structure-activity relationship of profens (i.e., 2-arylpropionic acid derivatives, a class of non-steroidal anti-inflammatory drugs) discusses the importance of α-monomethyl substitution ...
Highly efficient and versatile synthesis of polyarylfluorenes via Pd-catalyzed C-H bond activation.Org. Lett. 11(20) , 4588-91, (2009)
A facile protocol for the Pd-catalyzed preparative synthesis of fluorene derivatives has been developed. While a wide range of fluorenes were easily obtained with high efficiency and selectivity under...