o-Bromo(methylthio)benzene
Names
[ CAS No. ]:
19614-16-5
[ Name ]:
o-Bromo(methylthio)benzene
[Synonym ]:
1-Bromo-2-(methylsulfanyl)benzene
2-(methylthio)bromo benzene
1-Bromo-2-(methylthio)benzene
EINECS 243-183-4
Benzene, 1-bromo-2-(methylthio)-
2-Br-phenyl methyl sulfide
2-BroMothioanisole
1-methylthio-2-bromobenzene
2-Bromophenyl methyl sulphide
o-Bromothioanisole
2-Bromo Thioanisole
2-Bromophenyl methyl sulfide
o-Bromo(methylthio)benzene
MFCD00000066
Chemical & Physical Properties
[ Density]:
1.5±0.1 g/cm3
[ Boiling Point ]:
258.8±0.0 °C at 760 mmHg
[ Melting Point ]:
-24 °C
[ Molecular Formula ]:
C7H7BrS
[ Molecular Weight ]:
203.100
[ Flash Point ]:
95.0±22.6 °C
[ Exact Mass ]:
201.945175
[ PSA ]:
25.30000
[ LogP ]:
3.64
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.624
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R22;R36/37/38
[ Safety Phrases ]:
S37/39-S26
[ RIDADR ]:
UN 3334
[ HS Code ]:
2930909090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2930909090
[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Angew. Chem. Int. Ed. Engl. 48(27) , 4957-60, (2009)
Going fishing! The sulfonium borane [1](+) complexes cyanide in pure water at the maximum allowable concentration of 50 ppb recommended by the European Union. The high cyanide ion affinity displayed b...
Isolation of S-(bromophenyl)cysteine isomers from liver proteins of bromobenzene-treated rats.Chem. Res. Toxicol. 4(1) , 17-20, (1991)
The thioether-methyleneborane (PhSCH2B (C6F5) 2) 2: synthesis and reactivity with donors and alkynes. Tanur CA and Stephan DW.
Organometallics 30(13) , 3652-57, (2011)