Methyl 1-cyclohexene-1-carboxylate

Names

[ Name ]:
Methyl 1-cyclohexene-1-carboxylate

[Synonym ]:
Methyl cyclohex-1-enecarboxylate
1-Cyclohexene-1-carboxylic acid,methyl ester
Methyl 1-Cyclohexenecarboxylate
Methyl 1-cyclohexene-1-carboxylate
1-Cyclohexen-1-carbonsaeure-methylester
methyl cyclohexenecarboxylate
cyclohex-1-enecarboxylic acid methyl ester
Methyl cyclohex-1-ene-1-carboxylate
MFCD00001544
cyclohexene-1-carboxylic acid methyl ester
EINECS 242-331-5

Chemical & Physical Properties

[ Density]:
1.028 g/mL at 20 °C(lit.)

[ Boiling Point ]:
190-192 °C

[ Molecular Formula ]:
C₈H₁₂O₂

[ Molecular Weight ]:
140.18000

[ Flash Point ]:
165 °F

[ Exact Mass ]:
140.08400

[ PSA ]:
26.30000

[ LogP ]:
1.65980

[ Vapour Pressure ]:
0.463mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.477

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Safety Phrases ]:
S23-S24/25

[ WGK Germany ]:
3

[ HS Code ]:
2916209090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2916209090

[ Summary ]:
2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

Articles

Ceric ammonium nitrate (CAN)-mediated oxidative cycloaddition of 1, 3-dicarbonyls to conjugated compounds. Efficient synthesis of dihydrofurans, dihydrofurocoumarins, dihydrofuroquinolinones, dihydrofurophenalenones, and furonaphthoquinone natural products. Lee YR, et al.

Tetrahedron 56(45) , 8845-53, (2000)

Diastereoselective Synthesis of cis-1, 2-Dialkenylcyclopropanols and Subsequent Oxy-Cope Rearrangement. Lee J, et al.

J. Am. Chem. Soc. 117(39) , 9919-20, (1995)

Related Compounds

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