(TRIFLUOROMETHYL)DICHLOROPHOSPHINE

Names

[ Name ]:
(TRIFLUOROMETHYL)DICHLOROPHOSPHINE

[Synonym ]:
2-(trimethylsilyl)acetonitrile
TMSAN
EINECS 242-169-5
trimethylsilylmethylisocyanide
MFCD00001882
(Cyanomethyl)trimethylsilane
(Trimethylsilyl)acetonitrile

Chemical & Physical Properties

[ Density]:
0.807g/cm3

[ Boiling Point ]:
162.2ºC at 760mmHg

[ Molecular Formula ]:
C₅H₁₁NSi

[ Molecular Weight ]:
113.23300

[ Flash Point ]:
50ºC

[ Exact Mass ]:
113.06600

[ PSA ]:
23.79000

[ LogP ]:
1.84818

[ Appearance of Characters ]:
Liquid | Clear colorless to straw

[ Vapour Pressure ]:
2.19mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.420(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H301 + H311 + H331-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2931900090

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Lewis base-catalyzed cyanomethylation of carbonyl compounds with (trimethylsilyl) acetonitrile. Kawano Y, et al.

Chem. Lett. 34(11) , 1508-9, (2005)