1-[(Triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one

Names

[ CAS No. ]:
181934-30-5

[ Name ]:
1-[(Triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one

[Synonym ]:
1-[(Triisopropylsilyl)ethynyl]-1λ,2-benziodoxol-3(1H)-one
1-[2-tri(propan-2-yl)silylethynyl]-1λ<sup>3</sup>,2-benziodoxol-3-one
1-{[Tris-(1-methylethyl)silyl]ethynyl]}-1,2-benziodoxol-3(1H)-one TIPS-EBX

Chemical & Physical Properties

[ Melting Point ]:
170 °C(dec.)

[ Molecular Formula ]:
C₁₈H₂₅IO₂Si

[ Molecular Weight ]:
428.380

[ Exact Mass ]:
428.066833

[ PSA ]:
26.30000

[ LogP ]:
5.62690

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335-H413

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ RIDADR ]:
NONH for all modes of transport

Articles

Pd-catalyzed intramolecular oxyalkynylation of alkenes with hypervalent iodine.

Org. Lett. 12 , 384-387, (2010)

The first example of intramolecular oxyalkynylation of nonactivated alkenes using oxidative Pd chemistry is reported. Both phenol and aromatic or aliphatic acid derivatives could be used under operato...

Direct alkynylation of indole and pyrrole heterocycles.

Angew. Chem. Int. Ed. Engl. 48 , 9346-9349, (2009)