(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)
Names
[ CAS No. ]:
174810-09-4
[ Name ]:
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)
[Synonym ]:
MFCD02684551
(R,R)-DACH-naphthyl trost ligand
2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide
Chemical & Physical Properties
[ Melting Point ]:
224-231ºC
[ Molecular Formula ]:
C52H44N2O2P2
[ Molecular Weight ]:
790.86500
[ Exact Mass ]:
790.28800
[ PSA ]:
85.38000
[ LogP ]:
9.76220
MSDS
Safety Information
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
26-36/37/39
[ RIDADR ]:
NONH for all modes of transport
Precursor & DownStream
Precursor
DownStream
Articles
Chem. Rev. 96 , 395, (1996)
Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
Chem. Rev. 103 , 2921, (2003)
Trost, B.M. et al.
J. Am. Chem. Soc. 124 , 11616, (2004)