4-Cyanobenzyl bromide

Names

[ Name ]:
4-Cyanobenzyl bromide

[Synonym ]:
EINECS 241-246-0
Benzonitrile, p-(bromomethyl)-
4-(Brommethyl)benzolcarbonitril
alpha-Bromo-p-tolunitrile
p-Toluonitrile, α-bromo-
MFCD00001829
4-(Bromomethyl)benzonitrile
Benzonitrile, 4- (bromomethyl)-
Benzonitrile, 4-(bromomethyl)-
p-(Bromomethyl)benzonitrile
NCR D1E
p-Tolunitrile, α-bromo-
p-Cyanobenzyl bromide
α-Bromo-p-tolunitrile
4-cyanobenzyl bromide

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
283.2±23.0 °C at 760 mmHg

[ Melting Point ]:
115-117 °C(lit.)

[ Molecular Formula ]:
C₈H₆BrN

[ Molecular Weight ]:
196.044

[ Flash Point ]:
125.1±22.6 °C

[ Exact Mass ]:
194.968353

[ PSA ]:
23.79000

[ LogP ]:
2.36

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.588

[ Storage condition ]:
Store at 0-5°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H334

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S22-S26-S36/37/39-S45-S28A

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2926909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

4-[(2H-Tetra-zol-2-yl)meth-yl]benzonitrile.

Acta Crystallogr. Sect. E Struct. Rep. Online 64(Pt 2) , o445, (2008)

The title compound, C(9)H(7)N(5), was synthesized by reaction of 4-(bromomethyl)benzonitrile and 2H-tetrazole in the presence of KOH. The relative orientation of the planar tetra-zole ring and the met...

Hierarchical self-assembly of heteronuclear co-ordination networks.

Dalton Trans. 39(16) , 3805-15, (2010)

Two ligands L(1) and L(2) have been prepared which contain a chelating pyrazolyl-pyridine group with a pendant aromatic nitrile (in L(1), a benzonitrile; in L(2), a naphthonitrile). These ligands reac...