(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N-bis(2-diphenylphosphinobenzoyl)
Names
[ CAS No. ]:
169689-05-8
[ Name ]:
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N-bis(2-diphenylphosphinobenzoyl)
[Synonym ]:
Trost ligand
N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]
MFCD01631274
2-diphenylphosphanyl-N-[(1S,2S)-2-[(2-diphenylphosphanylbenzoyl)amino]cyclohexyl]benzamide
Trost's ligand
(S,S)-DACH-phenyl Trost ligand
Benzamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
Chemical & Physical Properties
[ Boiling Point ]:
817.0±65.0 °C at 760 mmHg
[ Melting Point ]:
134-136ºC
[ Molecular Formula ]:
C44H40N2O2P2
[ Molecular Weight ]:
690.748
[ Flash Point ]:
447.9±34.3 °C
[ Exact Mass ]:
690.256531
[ PSA ]:
85.38000
[ LogP ]:
9.87
[ Vapour Pressure ]:
0.0±2.9 mmHg at 25°C
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
S36-S37-S39
[ RIDADR ]:
NONH for all modes of transport
Articles
Chem. Rev. 96 , 395, (1996)
Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
Chem. Rev. 103 , 2921, (2003)
Trost, B.M. et al.
J. Am. Chem. Soc. 124 , 11616, (2004)