Dichlororuthenium-triphenylphosphine (1:3)

Names

[ Name ]:
Dichlororuthenium-triphenylphosphine (1:3)

[Synonym ]:
Dichlorotris(triphenylphosphine)ruthenium(II)
Ruthenium(2+) chloride triphenylphosphine (1:2:3)
Tris(triphenylphosphine)ruthenium(II) dichloride
Dichlororuthenium - triphenylphosphine (1:3)
Phosphine, triphenyl-, ruthenium(2+) salt, hydrochloride (3:1:2)
EINECS 239-569-7
Dichlorotris(triphenylphosphino)ruthenium (II)
MFCD00013077
Tris(triphenylphosphine)ruthenium(II) chloride
Tris(triphenylphosphine)ruthenium(II)chloride

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760 mmHg

[ Melting Point ]:
159 °C

[ Molecular Formula ]:
C₅₄H₄₅Cl₂P₃Ru

[ Molecular Weight ]:
958.832

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
958.115479

[ PSA ]:
40.77000

[ LogP ]:
11.71340

[ Vapour Pressure ]:
4.74E-05mmHg at 25°C

[ Storage condition ]:
Refrigerator

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21

[ Safety Phrases ]:
S36/37-S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Articles

Transition-metal-catalyzed rearrangement of allenyl sulfides: a route to furan derivatives.

Angew. Chem. Int. Ed. Engl. 46 , 1905, (2007)

Cross-coupling reaction between alcohols through sp3 C-H activation catalyzed by a ruthenium/Lewis acid system.

Chemistry 33th ed., 14 , 10201-10205, (2008)