methyl penta-2,4-dienoate
Names
[ CAS No. ]:
1515-75-9
[ Name ]:
methyl penta-2,4-dienoate
[Synonym ]:
penta-2,4-dienoic acid methyl ester
2,4-pentadienoic acid methyl ester
methyl 1,3-butadiene-1-carboxylate mixt. of cis/trans
methyl pentadienate
METHYL 1,3-BUTADIENE-1-CARBOXYLATE
Dimethyl-2,4-pentandioate
Penta-2,4-diensaeure-methylester
1-methoxycarbonyl-1,3-butadiene
METHYL 1,3-BUTADIENE-1-CARBOXYLATE MIXT. OF CIS/TRANS,STAB.
METHYL 2,4-PENTADIENOATE
Vynilacrylic acid methyl ester
1-methoxycarbonylbuta-1,3-diene
methyl penta-2,4-dienoate
Chemical & Physical Properties
[ Density]:
0.936g/cm3
[ Boiling Point ]:
135.2ºC at 760mmHg
[ Molecular Formula ]:
C6H8O2
[ Molecular Weight ]:
112.12700
[ Flash Point ]:
46.4ºC
[ Exact Mass ]:
112.05200
[ PSA ]:
26.30000
[ LogP ]:
0.90160
[ Vapour Pressure ]:
7.8mmHg at 25°C
[ Index of Refraction ]:
n20/D 1.484
[ Storage condition ]:
−20°C
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H315-H319-H335-H412
[ Precautionary Statements ]:
P261-P273-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
10-36/37/38
[ Safety Phrases ]:
26-36
[ RIDADR ]:
UN 3272 3/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
Synthetic Route
Articles
J. Org. Chem. 72(9) , 3326-31, (2007)
The aza-Morita-Baylis-Hillman reactions of aldimines 2 with several activated conjugated dienes were found to proceed smoothly in DMF in the presence of 3-hydroxyquinuclidine (HQD). Imines 2 reacted w...