methyl (phenylsulfinyl)acetate

Names

[ Name ]:
methyl (phenylsulfinyl)acetate

[Synonym ]:
MFCD00002087
methyl benzenesulfinylacetate
Methyl 2-phenylsulfinylacetate
EINECS 237-936-6
Methyl(phenylsulfinyl)acetate
DL-methyl (phenylsulfinyl)acetate
GNF-Pf-1921

Chemical & Physical Properties

[ Density]:
1.29g/cm3

[ Boiling Point ]:
130-131ºC0.5 mm Hg(lit.)

[ Melting Point ]:
52-54ºC(lit.)

[ Molecular Formula ]:
C₉H₁₀O₃S

[ Molecular Weight ]:
198.23900

[ Flash Point ]:
164.2ºC

[ Exact Mass ]:
198.03500

[ PSA ]:
62.58000

[ LogP ]:
1.83290

[ Vapour Pressure ]:
8.15E-05mmHg at 25°C

[ Index of Refraction ]:
1.584

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

J. Chem. Soc. Perkin Trans. I , 2683, (1991)

Phase-Transfer Catalyzed Alkylative Elimination of Methyl 2-Phenylsulfinylacetate. A One-Pot Synthesis of Substituted Cinnamates. Chong-ying X, et al.

Synth. Commun. 17(15) , 1839-43, (1987)

New Synthetic reactions. Alkylative elimination. Trost BM, et al.

J. Am. Chem. Soc. 96(22) , 7165-67, (1974)