(1R,2R)-Trost ligand
Names
[ CAS No. ]:
138517-61-0
[ Name ]:
(1R,2R)-Trost ligand
[Synonym ]:
Trost ligand
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl)
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
(R,R)-DACH-Phenyl Trost Ligand
MFCD01631273
Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
(1R,2R)-(+)-N,N'-Bis(2-diphenylphosphinobenzoyl)-1,2-diaminocyclohexane
N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]
2-Diphenylphosphanyl-N-[(1R,2R)-2- [(2-diphenylphosphanylbenzoyl) amino]cyclohexyl]benzamide
2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylbenzoyl)amino]cyclohexyl]benzamide
Chemical & Physical Properties
[ Boiling Point ]:
817.0±65.0 °C at 760 mmHg
[ Melting Point ]:
134-136ºC
[ Molecular Formula ]:
C44H40N2O2P2
[ Molecular Weight ]:
690.748
[ Flash Point ]:
447.9±34.3 °C
[ Exact Mass ]:
690.256531
[ PSA ]:
85.38000
[ LogP ]:
9.87
[ Vapour Pressure ]:
0.0±2.9 mmHg at 25°C
MSDS
Safety Information
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
26-36/37/39
[ RIDADR ]:
NONH for all modes of transport
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Chem. Rev. 96 , 395, (1996)
Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
Chem. Rev. 103 , 2921, (2003)
Trost, B.M. et al.
J. Am. Chem. Soc. 124 , 11616, (2004)