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Potassium ferricyanide

Names

[ CAS No. ]:
13746-66-2

[ Name ]:
Potassium ferricyanide

[Synonym ]:
Potassium hexacyanoferrate(III)
Potassium ferricyanide
MFCD00011392
EINECS 237-323-3
Red prussiate

Chemical & Physical Properties

[ Density]:
1.85

[ Boiling Point ]:
25.7ºC at 760 mmHg

[ Melting Point ]:
°Cd ec.)

[ Molecular Formula ]:
C6FeK3N6

[ Molecular Weight ]:
329.24400

[ Exact Mass ]:
328.84500

[ PSA ]:
142.74000

[ LogP ]:
0.09818

[ Storage condition ]:
Store at RT.

[ Stability ]:
Stable. Incompatible with ammonia, strong acids, strong oxidizing agents. Reaction with acids yields toxic gas. May discolour on exposure to light.

[ Water Solubility ]:
464 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LJ8225000
CHEMICAL NAME :
Ferrate(3-), hexacyano-, tripotassium
CAS REGISTRY NUMBER :
13746-66-2
LAST UPDATED :
199704
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C6-Fe-N6.3K
MOLECULAR WEIGHT :
329.27
WISWESSER LINE NOTATION :
NC-FE-CN&CN&CN&CN&CN &-KA- 3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2970 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
510 ug/m3/24H/26W-C
TOXIC EFFECTS :
Kidney, Ureter, Bladder - other changes in urine composition Blood - changes in erythrocyte (RBC) count Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - catalases

MUTATION DATA

TYPE OF TEST :
Gene conversion and mitotic recombination
TEST SYSTEM :
Yeast - Saccharomyces cerevisiae
DOSE/DURATION :
100 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 117,149,1983 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81080 No. of Facilities: 5391 (estimated) No. of Industries: 50 No. of Occupations: 41 No. of Employees: 27467 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81080 No. of Facilities: 3468 (estimated) No. of Industries: 55 No. of Occupations: 58 No. of Employees: 85385 (estimated) No. of Female Employees: 20227 (estimated)

Safety Information

[ Supplemental HS ]:
Contact with acids liberates very toxic gas.

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R32

[ Safety Phrases ]:
S50A

[ RIDADR ]:
UN3077 9/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
LJ8225000

[ HS Code ]:
2837200090

Customs

[ HS Code ]: 2837200090

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