Tri-tert-butylphosphine
Names
[ CAS No. ]:
13716-12-6
[ Name ]:
Tri-tert-butylphosphine
[Synonym ]:
EINECS 237-266-4
tritert-butylphosphane
P(t-Bu)3 P(t-Bu)3
MFCD00015006
Tri-t-Butylphosphine
Chemical & Physical Properties
[ Density]:
0.861 g/mL at 25 °C
[ Boiling Point ]:
229.4±9.0 °C at 760 mmHg
[ Melting Point ]:
30-35 °C(lit.)
[ Molecular Formula ]:
C12H27P
[ Molecular Weight ]:
202.316
[ Flash Point ]:
94.6±25.0 °C
[ Exact Mass ]:
202.185043
[ PSA ]:
13.59000
[ LogP ]:
4.50
[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C
[ Storage condition ]:
Flammables area
[ Water Solubility ]:
insoluble
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS07, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H250-H304-H314-H336-H361d-H373
[ Precautionary Statements ]:
P210-P280-P301 + P310-P302 + P334-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P331-P422
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable;C:Corrosive;
[ Risk Phrases ]:
R17;R34
[ Safety Phrases ]:
S26-S45-S62-S36/37/39-S25-S43-S27-S16
[ RIDADR ]:
UN 2846 4.2/PG 1
[ WGK Germany ]:
3
[ Packaging Group ]:
I
[ Hazard Class ]:
4.2
[ HS Code ]:
2931900090
Synthetic Route
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Org. Lett. 8 , 5725, (2006)
Inter- and intramolecular arylations of trimethylsilyl enol ethers with aryl halides are accomplished regiospecifically in the presence of a palladium catalyst and tributyltin fluoride in refluxing be...
Synlett , 2597, (2006)