1-Chloropinacolone
Names
[ CAS No. ]:
13547-70-1
[ Name ]:
1-Chloropinacolone
[Synonym ]:
1-chloro-3,3-dimethylbutan-2-one
1-chloro-3,3-dimethyl-butan-2-one
a-Chloropinacolin
CHLOROPINACOLONE
1-monochloropinacoline
1-Chloro-3,3-dimethyl-2-butanone
1-CHLOROPINACOLIN
2,2-dimethyl-4-chloro-butan-3-one
MFCD00035688
chloromethyl tert-butyl ketone
chlorpinakolin
Chloropinacoline
EINECS 236-920-6
MONOCHLOROPINAKOLONE
1-chlor-3,3-dimethylbutan-2-on
monochloropinacolone
2-Butanone, 1-chloro-3,3-dimethyl-
1-Chloropinacolone
tert-Butyl Chloromethyl Ketone
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
171.5±0.0 °C at 760 mmHg
[ Melting Point ]:
−13 °C(lit.)
[ Molecular Formula ]:
C6H11ClO
[ Molecular Weight ]:
134.604
[ Flash Point ]:
67.2±0.0 °C
[ Exact Mass ]:
134.049850
[ PSA ]:
17.07000
[ LogP ]:
1.65
[ Vapour Pressure ]:
1.4±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.423
[ Storage condition ]:
2-8°C
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- EL7078000
- CHEMICAL NAME :
- 2-Butanone, 1-chloro-3,3-dimethyl-
- CAS REGISTRY NUMBER :
- 13547-70-1
- LAST UPDATED :
- 199806
- DATA ITEMS CITED :
- 7
- MOLECULAR FORMULA :
- C6-H11-Cl-O
- MOLECULAR WEIGHT :
- 134.62
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 550 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(12),91,1987
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 355 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(12),91,1987
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 4600 mg/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(12),91,1987
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 675 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(12),91,1987 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 4675 mg/kg/17W-I
- TOXIC EFFECTS :
- Brain and Coverings - other degenerative changes Kidney, Ureter, Bladder - other changes Related to Chronic Data - death
- REFERENCE :
- MTPEEI Meditsina Truda i Promyshlennaya Ekologiya. Industrial Medicine and Ecology. (Mezhdunarodnaya Kniga, ul.B. Yakimanka, 39 117049 Moscow, Russia) No.1- 1993- Volume(issue)/page/year: (7),31,1997
Safety Information
[ Symbol ]:
GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H302-H311-H315-H319-H330-H335
[ Precautionary Statements ]:
P260-P280-P284-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
T+:Verytoxic;
[ Risk Phrases ]:
R22;R24;R26;R36/37/38
[ Safety Phrases ]:
S26-S36-S45-S38-S36/37/39-S28A
[ RIDADR ]:
UN 2810
[ WGK Germany ]:
3
[ RTECS ]:
EL7078000
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
[ HS Code ]:
2914700090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2914700090
[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%
Articles
Gig. Sanit. (1) , 61-2, (1992)