1,3-dithian-2-yl(trimethyl)silane

Names

[ Name ]:
1,3-dithian-2-yl(trimethyl)silane

[Synonym ]:
1,3-Dithian-2-yltrimethylsilane
(1,3-Dithian-2-yl)trimethylsilane
2-Trimethylsilyl-1,3-dithiane
1,3-dithian-2-yl(trimethyl)silane
Silane, 1,3-dithian-2-yltrimethyl-
EINECS 236-504-4
MFCD00006655

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
261.7±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₁₆S₂Si

[ Molecular Weight ]:
192.417

[ Flash Point ]:
96.1±0.0 °C

[ Exact Mass ]:
192.046265

[ PSA ]:
50.60000

[ LogP ]:
2.65

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.513

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
3334

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Multicomponent linchpin couplings. Reaction of dithiane anions with terminal epoxides, epichlorohydrin, and vinyl epoxides: efficient, rapid, and stereocontrolled assembly of advanced fragments for complex molecule synthesis.

J. Am. Chem. Soc. 125 , 14435, (2003)

The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading...

Lewis base catalyzed 1,3-dithiane addition to carbonyl and imino compounds using 2-trimethylsilyl-1,3-dithiane.

Chem. Asian J. 3(8-9) , 1592-600, (2008)

Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines with 2-trimethylsilyl-1,3-dithiane (TMS-dithiane) is described. By the activation of ...

Smith, A. B., III; Boldi, A. M.

J. Am. Chem. Soc. 119 , 6925, (1997)