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Tungsten trioxide

Names

[ CAS No. ]:
1314-35-8

[ Name ]:
Tungsten trioxide

[Synonym ]:
D-Glucose,3-methanesulfonate
3-O-Mesyl-D-glucose
Tungsten Trioxide
EINECS 215-231-4
O3-Mesyl-D-glucose
Tungstic anhydride
O3W,tetragonal
MFCD00011466
Tungsten(VI) oxide

Chemical & Physical Properties

[ Density]:
7.16 g/mL at 25 °C(lit.)

[ Boiling Point ]:
~1700ºC

[ Melting Point ]:
1470-1475 °C

[ Molecular Formula ]:
O3W

[ Molecular Weight ]:
231.83800

[ Exact Mass ]:
231.93600

[ PSA ]:
51.21000

[ Water Solubility ]:
insoluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YO7760000
CHEMICAL NAME :
Tungsten oxide
CAS REGISTRY NUMBER :
1314-35-8
LAST UPDATED :
199712
DATA ITEMS CITED :
19
MOLECULAR FORMULA :
O3-W
MOLECULAR WEIGHT :
231.85
WISWESSER LINE NOTATION :
.WO..O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1059 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - excitement Behavioral - muscle weakness
REFERENCE :
HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 31(7-9),197,1966
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(7),71,1983 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
490 ug/m3/24H/15W-C
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(7),71,1983 *** REVIEWS *** ACGIH TLV-TWA 5 mg(W)/m3; STEL 10 mg(W)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 mg(W)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,272,1971 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(W)/m3;STEL 10 mg(W)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(W)/m3;STEL 10 mg(W)/m3 JAN 1993 OEL-DENMARK:TWA 5 mg(W)/m3 JAN 1993 OEL-FINLAND:TWA 5 mg(W)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 5 mg(W)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg(W)/m3 JAN 1993 OEL-SWEDEN:TWA 5 mg(W)/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg(W)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(W)/m3;STEL 10 mg(W)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO TUNGSTEN, insoluble-air:TWA 5 mg(W)/m3;STEL 10 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84213 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 21 (estimated)

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
-

[ RTECS ]:
YO7760000

[ HS Code ]:
2825901200

Customs

[ HS Code ]: 2825901200

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Mesoporous carbon nitride-tungsten oxide composites for enhanced photocatalytic hydrogen evolution.

ChemSusChem , doi:10.1002/cssc.201403278, (2015)

Composites of mesoporous polymeric carbon nitride and tungsten(VI) oxide show very high photocatalytic activity for the evolution of hydrogen from water under visible light and in the presence of sacr...

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