chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II)
Names
[ CAS No. ]:
1310584-14-5
[ Name ]:
chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II)
[Synonym ]:
XPhos Pd G2
Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II)
Chemical & Physical Properties
[ Melting Point ]:
202-210 °C
[ Molecular Formula ]:
C45H57ClNPPd
[ Molecular Weight ]:
784.78800
[ Exact Mass ]:
783.29500
[ PSA ]:
13.59000
[ LogP ]:
14.05890
MSDS
Safety Information
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
36/37/38
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3.0
Articles
J. Org. Chem. 78(8) , 4123-31, (2013)
A method has been developed for the Pd-catalyzed synthesis of α-(hetero)aryl esters and amides through a Suzuki-Miyaura cross-coupling reaction. This method avoids the use of strong base, does not nec...
Pd-catalyzed Suzuki-Miyaura cross-coupling reactions between sulfamates and potassium Boc-protected aminomethyltrifluoroborates.Org. Lett. 15(10) , 2534-7, (2013)
Sulfamates were studied as the electrophilic partners in the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction with potassium Boc-protected primary and secondary aminomethyltrifluoroborates. ...
Potassium Boc-protected secondary aminomethyltrifluoroborates: synthesis and Suzuki-Miyaura cross-coupling reactions.Org. Lett. 14(17) , 4458-61, (2012)
Seven potassium Boc-protected secondary aminomethyltrifluoroborates were prepared in a standardized two-step process. The Suzuki-Miyaura cross-coupling reaction was studied with this new class of nucl...