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dibutylmagnesium

Names

[ CAS No. ]:
1191-47-5

[ Name ]:
dibutylmagnesium

[Synonym ]:
EINECS 214-736-7
MFCD00015225
Di-N-butylmagnesium

Chemical & Physical Properties

[ Density]:
0.749 g/mL at 20 °C

[ Melting Point ]:
-71ºC

[ Molecular Formula ]:
C8H18Mg

[ Molecular Weight ]:
138.53400

[ Flash Point ]:
21 °F

[ Exact Mass ]:
138.12600

[ LogP ]:
3.50820

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H224-H250-H260-H302-H304-H314-H336-H361f-H373-H412

[ Supplemental HS ]:
May form explosive peroxides., Reacts violently with water.

[ Precautionary Statements ]:
P210-P231 + P232-P280-P301 + P310-P302 + P334-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P331-P370 + P378-P403 + P235-P422

[ Hazard Codes ]:
F+,C,T,F,N

[ Risk Phrases ]:
R12

[ Safety Phrases ]:
16-26-36/37/39-43-45-7/8-62-61-60

[ RIDADR ]:
UN 3399 4.3/PG 1

[ WGK Germany ]:
1

[ HS Code ]:
2931900090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Some novelties in olefin carbometallation assisted by alkyl-magnesium and-aluminium derivatives and catalyzed by zirconium and titanium complexes. Dzhemilev UM and Vostrikova OS

J. Organomet. Chem. 285(1) , 43-51, (1985)

Multivalent cation intercalation Bruce PG, et al.

Solid State Ionics 53-56(1) , 351-355, (1992)

Chemical and physical evidence for metal–metal interchange between lithium alkoxides and di-n-butylmagnesium. Micha Screttas M, et al.

Tetrahedron Lett. 43(27) , 4871-4873, (2002)


More Articles


Related Compounds