dibutylmagnesium
Names
[ CAS No. ]:
1191-47-5
[ Name ]:
dibutylmagnesium
[Synonym ]:
EINECS 214-736-7
MFCD00015225
Di-N-butylmagnesium
Chemical & Physical Properties
[ Density]:
0.749 g/mL at 20 °C
[ Melting Point ]:
-71ºC
[ Molecular Formula ]:
C8H18Mg
[ Molecular Weight ]:
138.53400
[ Flash Point ]:
21 °F
[ Exact Mass ]:
138.12600
[ LogP ]:
3.50820
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS07, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H224-H250-H260-H302-H304-H314-H336-H361f-H373-H412
[ Supplemental HS ]:
May form explosive peroxides., Reacts violently with water.
[ Precautionary Statements ]:
P210-P231 + P232-P280-P301 + P310-P302 + P334-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P331-P370 + P378-P403 + P235-P422
[ Hazard Codes ]:
F+,C,T,F,N
[ Risk Phrases ]:
R12
[ Safety Phrases ]:
16-26-36/37/39-43-45-7/8-62-61-60
[ RIDADR ]:
UN 3399 4.3/PG 1
[ WGK Germany ]:
1
[ HS Code ]:
2931900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
J. Organomet. Chem. 285(1) , 43-51, (1985)
Multivalent cation intercalation Bruce PG, et al.
Solid State Ionics 53-56(1) , 351-355, (1992)
Chemical and physical evidence for metal–metal interchange between lithium alkoxides and di-n-butylmagnesium. Micha Screttas M, et al.
Tetrahedron Lett. 43(27) , 4871-4873, (2002)