Diisobutylaluminium hydride
Names
[ CAS No. ]:
1191-15-7
[ Name ]:
Diisobutylaluminium hydride
[Synonym ]:
Hydrido(diisobutyl)aluminium
EINECS 214-729-9
DIBAH
Diisobutylaluminum hydride
Aluminum, hydrobis(2-methylpropyl)-
DIBAL
Di-iso-butylaluminum hydride
Hydrodiisobutylaluminum
MFCD00008928
bis(2-methylpropyl)aluminum
Diisobutylaluminium hydride
hidruro de diisobutilaluminio
Diisobutylhydroaluminum
DIBAL-H DIBAL
DIBAL-H
Diisobutylaluminumhydride
di-isobutylaluminium hydride
Hydrido(diisobutyl)aluminum
Chemical & Physical Properties
[ Density]:
1.23 g/mL at 25 °C
[ Boiling Point ]:
65 °C
[ Melting Point ]:
-70 °C
[ Molecular Formula ]:
C8H19Al
[ Molecular Weight ]:
142.218
[ Flash Point ]:
40 °F
[ Exact Mass ]:
142.130219
[ LogP ]:
3.33250
[ Storage condition ]:
2-8°C
[ Water Solubility ]:
vigorous reaction
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- BD0710000
- CHEMICAL NAME :
- Aluminum, diisobutylhydro-
- CAS REGISTRY NUMBER :
- 1191-15-7
- BEILSTEIN REFERENCE NO. :
- 4123663
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 14
- MOLECULAR FORMULA :
- C8-H19-Al
- MOLECULAR WEIGHT :
- 142.25
- WISWESSER LINE NOTATION :
- 1Y1&1-AL-H1Y1&1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 70 gm/m3/1H
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - other changes
- REFERENCE :
- MELAAD Medicina del Lavoro. Industrial Medicine. (Via S. Barnaba, 8, 20122 Milan, Italy) V.16- 1925- Volume(issue)/page/year: 57,188,1966 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS07, GHS08
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H250-H260-H304-H314-H336-H361d-H373
[ Precautionary Statements ]:
P210-P222-P223-P231 + P232-P370 + P378-P422
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable;C:Corrosive;
[ Risk Phrases ]:
R11;R14/15;R35;R48/20;R63;R65;R67
[ Safety Phrases ]:
S26-S43-S45-S62-S46-S36/37/39-S29-S16-S61-S27
[ RIDADR ]:
UN 3399 4.3/PG 1
[ WGK Germany ]:
2
[ RTECS ]:
BD0710000
[ Packaging Group ]:
I
[ Hazard Class ]:
4.3
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Talanta 134 , 256-63, (2015)
In this work a multivariate statistical tool (Derringer and Suich optimization) was proposed for the separation of seventeen capsinoids (natural and synthetic) using the UHPLC-DAD chromatography. Caps...
[Development of domino reactions based on skeletal rearrangement].Yakugaku Zasshi 131(11) , 1563-73, (2011)
Domino reactions, which enable formations of several chemical bonds and multi-step transformation in one-pot process, have received much attention as an efficient synthetic methodology to preserve che...
DIBAL-mediated reductive transformation of trans-dimethyl tartrate acetonide into ε-hydroxy α,β-unsaturated ester and its derivatives.J. Org. Chem. 76(11) , 4669-74, (2011)
Stepwise, selective DIBAL reduction of the acetonide diester derived from tartaric acid followed by the Horner-Emmons reaction effectively provided desymmetrized hydroxy mono-olefination products in a...