2-(allyldimethylsilyl)pyridine

Names

[ Name ]:
2-(allyldimethylsilyl)pyridine

[Synonym ]:
Pyridine,2-(dimethyl-2-propenylsilyl)
Allyldimethyl(2-pyridyl)silane
2-(Allyldimethylsilyl)pyridine
(2-pyridyl)allyldimethylsilane

Chemical & Physical Properties

[ Density]:
0.913 g/mL at 25ºC

[ Boiling Point ]:
223.9ºC at 760 mmHg

[ Molecular Formula ]:
C₁₀H₁₅NSi

[ Molecular Weight ]:
177.31800

[ Flash Point ]:
71ºC

[ Exact Mass ]:
177.09700

[ PSA ]:
12.89000

[ LogP ]:
2.18300

[ Vapour Pressure ]:
0.14mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.5046

[ Storage condition ]:
2-8°C

MSDS

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Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
UN 3334

Synthetic Route

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Precursor & DownStream

Precursor

DownStream

Articles

Palladium-catalyzed cross-coupling reactions of (2-pyridyl)allyldimethylsilanes with aryl iodides.

Org. Lett. 8 , 729, (2006)

[reaction: see text] (2-Pyridyl)allyldimethylsilanes were found to be novel pyridyl transfer reagents in palladium-catalyzed cross-coupling reactions of various aryl iodides in the presence of silver(...