tBuXPhos Pd G1
Names
[ CAS No. ]:
1142811-12-8
[ Name ]:
tBuXPhos Pd G1
[Synonym ]:
Chloropalladium(1+) (2-aminoethyl)benzenide - bis(2-methyl-2-propanyl)(2',4',6'-triisopropyl-2-biphenylyl)phosphine (1:1:1)
tBuXPhos Pd G1
Chemical & Physical Properties
[ Melting Point ]:
150-159℃
[ Molecular Formula ]:
C37H55ClNPPd
[ Molecular Weight ]:
686.686
[ Exact Mass ]:
685.279541
[ PSA ]:
39.61000
[ LogP ]:
8.12030
MSDS
Safety Information
[ Symbol ]:
GHS07, GHS08
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335-H351
[ Precautionary Statements ]:
P261-P281-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn
[ Risk Phrases ]:
36/37/38-40
[ Safety Phrases ]:
26-36/37
[ RIDADR ]:
NONH for all modes of transport
Articles
Acc. Chem. Res. 41 , 1461, (2008)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...
Biaryl phosphane ligands in palladium-catalyzed amination.Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...
Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.Chem. Sci. 2 , 27, (2011)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...