ISOPROPYLMAGNESIUM CHLORIDE

Names

[ CAS No. ]:
1068-55-9

[ Name ]:
ISOPROPYLMAGNESIUM CHLORIDE

[Synonym ]:
EINECS 213-947-1
magnesium,propane,chloride
MFCD00000466
IsopropylMagnesiuM Chloride

Chemical & Physical Properties

[ Density]:
0.98 g/mL at 20 °C

[ Boiling Point ]:
256 °C

[ Molecular Formula ]:
C₃H₇ClMg

[ Molecular Weight ]:
102.84600

[ Flash Point ]:
72 °F

[ Exact Mass ]:
102.00900

[ LogP ]:
2.05350

[ Storage condition ]:
Flammables + water-Freezer (-20°C)e area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H261-H314-H335-H351

[ Supplemental HS ]:
May form explosive peroxides., Reacts violently with water.

[ Precautionary Statements ]:
P210-P231 + P232-P280-P370 + P378-P402 + P404-P403 + P235

[ Hazard Codes ]:
F+: Highly flammable;C: Corrosive;

[ Risk Phrases ]:
R12;R14/15;R19;R22;R34;R66;R67

[ Safety Phrases ]:
S26-S36/37/39-S43-S45-S16-S33

[ RIDADR ]:
UN 3399 4.3/PG 2

[ WGK Germany ]:
1

Synthetic Route

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Precursor & DownStream

Precursor

DownStream

Articles

Direct, catalytic, and regioselective synthesis of 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles from N-oxides.

Org. Lett. 16(3) , 864-7, (2014)

A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of cop...