2-fluoro-5-methoxybenzaldehyde
Names
[ CAS No. ]:
105728-90-3
[ Name ]:
2-fluoro-5-methoxybenzaldehyde
[Synonym ]:
MFCD00070795
4-Fluoro-3-formylanisole
2-Fluoro-5-methoxybenzaldehyde
Benzaldehyde, 2-fluoro-5-methoxy-
VHR BF EO1
6-Fluoro-m-anisaldehyde
2-fluoro-5-methoxy-benzaldehyde
methyl 2-amino-3-(2-fluoro-5-hydroxyphenyl)propanoate
2-formyl-4-methoxyfluorobenzene
5-methoxy-2-fluorobenzaldehyde
6-fluoro-3-methoxybenzaldehyde
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
245.6±20.0 °C at 760 mmHg
[ Molecular Formula ]:
C8H7FO2
[ Molecular Weight ]:
154.138
[ Flash Point ]:
99.4±16.7 °C
[ Exact Mass ]:
154.043015
[ PSA ]:
26.30000
[ LogP ]:
1.87
[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C
[ Index of Refraction ]:
1.526
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn: Harmful;Xi: Irritant;
[ Risk Phrases ]:
R36/38
[ Safety Phrases ]:
S26-S36-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2913000090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2913000090
[ Summary ]:
HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%
Articles
J. Org. Chem. 76(10) , 3960-7, (2011)
The total synthesis of atroviridin has been accomplished by a linear route involving the N-heterocyclic carbene (NHC)-catalyzed aroylation of the fluorobenzene derivative, Claisen cyclization of the O...
Steric effects on atropisomerism in tetraarylporphyrins. Crossley MJ, et al.J. Am. Chem. Soc. 109(2) , 341-348, (1987)
A new synthesis of benzo [b] thiophenes utilizing an interrupted Pummerer reaction. Kobayashi K, et al.
Tetrahedron 65(12) , 2430-2435, (2009)