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2-Bromo-5-nitroaniline

Names

[ CAS No. ]:
10403-47-1

[ Name ]:
2-Bromo-5-nitroaniline

[Synonym ]:
2-Bromo-5-nitro aniline
Benzenamine,2-bromo-5-nitro
2-bromo-5-nitrophenylamine
EINECS 233-874-9
2-Brom-5-nitro-anilin
4-nitro-2-aminobromobenzene
Benzenamine, 2-bromo-5-nitro-
2-Bromo-5-nitroaniline
6-bromo-3-nitroaniline
MFCD00051578

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
334.5±22.0 °C at 760 mmHg

[ Melting Point ]:
139-141 °C(lit.)

[ Molecular Formula ]:
C6H5BrN2O2

[ Molecular Weight ]:
217.020

[ Flash Point ]:
156.1±22.3 °C

[ Exact Mass ]:
215.953430

[ PSA ]:
71.84000

[ LogP ]:
2.46

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.670

[ Water Solubility ]:
slightly soluble

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
UN 2811 6.1/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2921420090

Synthetic Route

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis and biological evaluation of A-ring biaryl-carbamate analogues of rhazinilam.

Bioorg. Med. Chem. 10(11) , 3395-400, (2002)

An improvement of the synthesis of biphenyl-carbamate 2a, the most active analogue of rhazinilam 1 so far, was performed using the Pd-catalyzed borylation/Suzuki coupling (BSC) method developed in our...

Formation and rearrangement of ipso intermediates in aromatic free-radical chlorination reactions. Everly CR and Traynham JG.

J. Org. Chem. 44(11) , 1784-1787, (1979)

An intramolecular palladium-catalysed aryl amination reaction to produce benzimidazoles. Brain CT and Brunton SA.

Tetrahedron Lett. 43(10) , 1893-95, (2002)


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