4-Methylbenzyl chloride
Names
[ CAS No. ]:
104-82-5
[ Name ]:
4-Methylbenzyl chloride
[Synonym ]:
Benzene, 1-(chloromethyl)-4-methyl-
α-Chloro-p-xylene
alpha-Chloro-p-xylene
4-Methyl benzyl chloride
EINECS 203-241-1
4-Methylbenzyl chloride
1-(Chloromethyl)-4-methylbenzene
MFCD00000919
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Boiling Point ]:
198.6±9.0 °C at 760 mmHg
[ Melting Point ]:
4 °C(lit.)
[ Molecular Formula ]:
C8H9Cl
[ Molecular Weight ]:
140.610
[ Flash Point ]:
75.6±0.0 °C
[ Exact Mass ]:
140.039276
[ LogP ]:
2.95
[ Vapour Pressure ]:
0.5±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.524
[ Storage condition ]:
2-8°C
[ Water Solubility ]:
Insoluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- ZE4030000
- CHEMICAL NAME :
- p-Xylene, alpha-chloro-
- CAS REGISTRY NUMBER :
- 104-82-5
- BEILSTEIN REFERENCE NO. :
- 0507387
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C8-H9-Cl
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 1100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 39(4),86,1974
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H302-H314
[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S27-S36/37/39-S45-S37/39
[ RIDADR ]:
UN 2922 8/PG 3
[ WGK Germany ]:
1
[ RTECS ]:
ZE4030000
[ Packaging Group ]:
III
[ Hazard Class ]:
8
[ HS Code ]:
2942000000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2903999090
[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
J. Appl. Toxicol. 3(4) , 203-7, (1983)
Benzyl chloride, benzyl bromide, p-methylbenzyl chloride, and p-nitrobenzyl chloride were used to study chemical reactivity with 4-(p-nitrobenzyl)-pyridine (NBP), and with guanosine in vitro, in relat...
Electrophilic attack at carbon-5 of guanine nucleosides: structure and properties of the resulting guanidinoimidazole products.IARC Sci. Publ. (70) , 235-40, (1986)