Formamide, N-phenyl-
Names
[ CAS No. ]:
103-70-8
[ Name ]:
Formamide, N-phenyl-
[Synonym ]:
N-Phenylformamide
ForManilide
EINECS 203-136-0
MFCD00003276
Chemical & Physical Properties
[ Density]:
1.144 g/mL at 25 °C(lit.)
[ Boiling Point ]:
166 °C14 mm Hg(lit.)
[ Melting Point ]:
46-48 °C(lit.)
[ Molecular Formula ]:
C7H7NO
[ Molecular Weight ]:
121.13700
[ Flash Point ]:
>230 °F
[ Exact Mass ]:
121.05300
[ PSA ]:
29.10000
[ LogP ]:
1.96380
[ Vapour Pressure ]:
0.00662mmHg at 25°C
[ Index of Refraction ]:
1.594
[ Storage condition ]:
0-10°C
[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- BY1780000
- CHEMICAL NAME :
- Aniline, N-formyl-
- CAS REGISTRY NUMBER :
- 103-70-8
- BEILSTEIN REFERENCE NO. :
- 0906934
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 5
- MOLECULAR FORMULA :
- C7-H7-N-O
- MOLECULAR WEIGHT :
- 121.15
- WISWESSER LINE NOTATION :
- VHMR
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 400 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC) Volume(issue)/page/year: 271,19,1941
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 400 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - muscle weakness Lungs, Thorax, or Respiration - respiratory stimulation
- REFERENCE :
- XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC) Volume(issue)/page/year: 271,19,1941
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Amphibian - frog
- DOSE/DURATION :
- 800 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- XPHBAO U.S. Public Health Service, Public Health Bulletin. (Washington, DC) Volume(issue)/page/year: 271,19,1941
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
22
[ Safety Phrases ]:
S22-S24/25
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
2
[ RTECS ]:
BY1780000
[ HS Code ]:
2924299090
Synthetic Route
Customs
[ HS Code ]: 2924299090
[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Angew. Chem. Int. Ed. Engl. 41(1) , 166-8, (2002)
Phosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds.
Chem. Commun. (Camb.) (29) , 3128-30, (2006)
The t-Bu-P4 base was found to be an excellent catalyst for the condensation of trimethylsilylacetate or trimethylacetonitrile with carbonyl compounds to form functionalized alkenes and beta-enaminoest...
Isomer selective infrared spectroscopy of supersonically cooled cis- and trans-N-phenylamides in the region from the amide band to NH stretching vibration.Phys. Chem. Chem. Phys. 11(29) , 6098-106, (2009)
We measured the infrared (IR) spectra of supersonically cooled N-phenylformamide (formanilide) and N-phenylacetamide (acetanilide) in the amide band and X-H stretch vibration regions by using IR-UV de...