3’-Bromo-4’-fluoroacetophenone

Names

[ Name ]:
3’-Bromo-4’-fluoroacetophenone

[Synonym ]:
EINECS 213-750-0
1-(3-Bromo-4-fluorophenyl)ethanone
3’-Bromo-4’-fluoroacetophenone
1-(3-Bromo-4-fluorophenyl)ethan-1-one
1-Acetyl-3-bromo-4-fluorobenzene
Ethanone, 1-(3-bromo-4-fluorophenyl)-
3'-Bromo-4'-fluoroacetophenone
3-Bromo-4-Fluoroacetophenone
MFCD00042466
3′-Bromo-4′-fluoroacetophenone
FR BE DV1

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
265.3±25.0 °C at 760 mmHg

[ Melting Point ]:
52-57 °C(lit.)

[ Molecular Formula ]:
C₈H₆BrFO

[ Molecular Weight ]:
217.035

[ Flash Point ]:
114.3±23.2 °C

[ Exact Mass ]:
215.958603

[ PSA ]:
17.07000

[ LogP ]:
2.55

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.534

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Palladium-catalyzed amination of 3-bromo-4-fluoro-acetophenone. Sun L-Q, et al.

Tetrahedron Lett. 43(51) , 9291-94, (2002)