Potassium osmate(VI) dihydrate
Names
[ CAS No. ]:
10022-66-9
[ Name ]:
Potassium osmate(VI) dihydrate
[Synonym ]:
Potassium Osmate (VI) Dihydrate
MFCD00149919
Osmium, diolatodioxo-, potassium salt, hydrate (1:2:2)
dipotassium,dioxido(dioxo)osmium,dihydrate
POTASSIUM OSMATE(VI) DIHYDRATE
Potassium dioxidodioxoosmium dihydrate
Potassium osmate dihydrate
EINECS 243-247-1
Potassium dioxido(dioxo)osmium hydrate (2:1:2)
Chemical & Physical Properties
[ Molecular Formula ]:
H4K2O6Os
[ Molecular Weight ]:
368.455
[ Exact Mass ]:
369.889709
[ PSA ]:
98.72000
[ Storage condition ]:
Store below +30°C.
[ Stability ]:
hygroscopic
[ Water Solubility ]:
Soluble in water. Slowly decomposes in aqueous solution forming the tetroxide. Insoluble in alcohol, etherSoluble in water. Insoluble in alcohol and ether.
MSDS
Safety Information
[ Symbol ]:
GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301 + H311 + H331
[ Precautionary Statements ]:
P261-P280-P301 + P310-P311
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ Hazard Codes ]:
O:Oxidizing;C:Corrosive;
[ Risk Phrases ]:
R34;R8
[ Safety Phrases ]:
S17-S26-S36/37/39-S45
[ RIDADR ]:
UN 3288 6.1/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
[ HS Code ]:
28439090
Customs
[ HS Code ]: 2915900090
[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
Articles
Tetrahedron Lett. 47 , 3797, (2006)
N-sulfonyloxy carbamates as reoxidants for the tethered aminohydroxylation reaction.
J. Am. Chem. Soc. 128 , 2514, (2006)
The use of N-sulfonyloxy carbamates as reoxidants for the tethered aminohydroxylation (TA) reaction is reported. These new conditions obviate the requirement for lithium hydroxide and tBuOCl in the ox...