Selenium dioxide reaction of substituted diphenacyl sulfides: generation of α-ketoacids

…, M Boominathan, S Muthusubramanian…

Index: Nagaraj, Muthupandi; Perumal, Devanathan; Boominathan, Muthusamy; Muthusubramanian, Shanmugam; Bhuvanesh, Nattamai Journal of Sulfur Chemistry, 2014 , vol. 35, # 1 p. 24 - 30

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Abstract

Selenium dioxide, which is used as a key component in the chemistry reported in this manuscript, is a very useful and versatile reagent for the synthesis of various types of organic compounds. The reagent is particularly useful for allylic oxidation 11. (a) Sharpless, KB; Lauer, RF J. Am. Chem. Soc. 1972, 94, 7154–7155; (b) Arigoni, D.; Vasella, A.; Sharpless, KB; Jensen, HP J. Am. Chem. Soc. 1973, 95, 7917–7919; (c) Stephenson, LM; Speth, DR ...