Tin (II) Chloride Catalyzed Synthesis of. BETA.-D-Ribonucleosides.
T Mukaiyama, T Matsutani, N Shimomura
Index: Mukaiyama, Teruaki; Matsutani, Takafumi; Shimomura, Naoyuki Chemistry Letters, 1994 , # 11 p. 2089 - 2092
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Abstract
Several β-D-ribonucleosides are stereoselectively synthesized in high yields from methyl 2, 3, 5-tri-O-benzoyl-β-D-ribofuranosyl carbonate and trimethylsilylated nucleoside bases such as pertrimethylsilylated uracil and adenine under mild conditions by using a catalytic amount of tin (II) chloride, a weak Lewis acid.
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