Organic letters

Platinum-Catalyzed Aromatization of Enediynes via a CH Bond Insertion of Tethered Alkanes

BP Taduri, YF Ran, CW Huang, RS Liu

Index: Taduri, Bhanu Pratap; Ran, Ying-Fen; Huang, Chun-Wei; Liu, Rai-Shung Organic Letters, 2006 , vol. 8, # 5 p. 883 - 886

Full Text: HTML

Citation Number: 46

Abstract

PtCl2 (5 mol%) is an effective catalyst for aromatization of enediynes via a CH bond insertion of tethered alkanes. The reaction mechanism of this cyclization is proposed to involve platinum-π-alkyne intermediates. This cyclization works not only for terminal alkynes but also for internal alkynes.

Related Articles:

Rhodium (II)??Catalyzed Cyclization of Bis (N??tosylhydrazone) s: An Efficient Approach towards Polycyclic Aromatic Compounds

[Xia, Ying; Liu, Zhenxing; Xiao, Qing; Qu, Peiyuan; Ge, Rui; Zhang, Yan; Wang, Jianbo Angewandte Chemie - International Edition, 2012 , vol. 51, # 23 p. 5714 - 5717]

A novel acid-catalyzed rearrangement of cyclobutanols

[Lee-Ruff, Edward; Hopkinson, Alan C.; Kazarians-Moghaddam, Hira; Duperrouzel, Paul; Gupta, Brij; Katz, Morris Tetrahedron Letters, 1981 , vol. 22, # 49 p. 4917 - 4920]

Substituent effects and aryl participation in. beta.-(syn-9-benzonorbornenyl) ethyl p-bromobenzenesulfonate solvolyses

[Muneyuki,R.; Tanida,H. Journal of the American Chemical Society, 1968 , vol. 90, p. 656 - 662]

Ring enlargements. XI. Structural influences on the course of the intramolecular diazo alkane-carbonyl reaction

[Gutsche,C.D.; Bowers,J.E. Journal of Organic Chemistry, 1967 , vol. 32, p. 1203 - 1212]

Ring enlargements. XI. Structural influences on the course of the intramolecular diazo alkane-carbonyl reaction

[Gutsche,C.D.; Bowers,J.E. Journal of Organic Chemistry, 1967 , vol. 32, p. 1203 - 1212]

More Articles...