Oxidation of the cyclopentanone and cyclohexanone alkyl derivatives in a pseudohomogeneous system without a phase transfer agent

…, OA Sadygov, MY Abdullaeva, NA Dzhafarova

Index: Alimardanov; Garibov; Abbasov; Sadygov; Abdullaeva; Dzhafarova Russian Journal of General Chemistry, 2011 , vol. 81, # 8 p. 1664 - 1670

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Abstract

Abstract The reaction of catalytic oxidation of C 5–C 12 alkyl-and cycloalkylcyclopentanones and-cyclohexanones to lactones in a pseudohomogeneous system without the participation of phase transfer agents was investigated. It was established that the catalytic systems prepared on the basis of molybdenum and tungsten blue (MeO n Br m, where Me= Mo, W, n= 1, 2, m= 2, 3) and H 3 PO 4 deposited on powdered activated carbon AG-3 at 40–60° C ...