Chemistry of organic chloramines. Formation of arenesulfonamides by derivatization of organic chloramines with sodium arenesulfinates

FE Scully Jr, K Bowdring

Index: Scully, Frank E.; Bowdring, Katherine Journal of Organic Chemistry, 1981 , vol. 46, p. 5077 - 5081

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Citation Number: 26

Abstract

Organic chloramines react rapidly with sodium benzenesulfinate or sodium toluenesulfinate to form arenesulfonamides. Derivatization was carried out by three different methods, one involving derivatization of pure chloramines and two involving derivatization of the chloramines generated in situ by reaction of the amine with sodium hypochlorite. Seventeen arenesulfonamides whose amine precursors included primary and secondary aliphatic ...