Biomacromolecules

Reactivity of vinyl ethers and vinyl ribosides in UV-initiated free radical copolymerization with acceptor monomers

L Pichavant, C Guillermain, X Coqueret

Index: Pichavant, Loic; Guillermain, Ce Line; Coqueret, Xavier Biomacromolecules, 2010 , vol. 11, # 9 p. 2415 - 2421

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Citation Number: 12

Abstract

The reactivity of various vinyl ethers and vinyloxy derivatives of ribose in the presence of diethyl fumarate or diethyl maleate was investigated for evaluating the potential of donor− acceptor-type copolymerization applied to unsaturated monomers derived from renewable feedstock. The photochemically induced polymerization of model monomer blends in the bulk state was monitored by infrared spectroscopy. The method allowed us to examine the ...