A NEW, MILD PREPARATION OF 2, 4, 6-TRINITROFLUOROBENZENE

JM Dust, RA Mandeville

Index: Dust, Julian M.; Manderville, Richard A. Organic Preparations and Procedures International, 1992 , vol. 24, # 1 p. 55 - 57

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Abstract

We have had a long standing interest in the mctions and mechanisms of reaction of 2, 4, 6- uinitrophenyl (picryl) derivatives, including picryl ethers, with nucleophiles.* 2 It has been suggested that picryl ethers are best prepared by reaction of the appropriate alcohol with picryl fluoride, in the presence of 1, 4-diazabicyclo [2.2. 2] octane, as catalyst? However, the two common methods for preparation of the precursor fluoride have significant drawbacks. ...