Highly cross-linked networks for dental applications obtained by photocuring of tris[2-(acryloyloxy)ethyl]isocyanurate, 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate, and pentaerythritol triacrylate.

J Nie, L A Lindén, J F Rabek, J Ekstrand

Index: Acta Odontol. Scand. 57(1) , 1-8, (1999)

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Abstract

Highly cross-linked networks have been obtained by photoinitiated camphorquinone-amine polymerization of tris[2-(acryloyloxy)ethyl]isocyanurate alone and/or with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate or pentaerythritol triacrylate, which can be considered a new class of dental restorative resins. The most effective coinitiators in this system are amines such as ethyl-4-dimethylaminobenzoate, N,N-dimethyl-benzylamine, and 2,4,6-tris(dimethylaminomethyl)phenol. The volume shrinkages of polymerized samples were 8%-13%. The hardness of photocured resins in the presence of an inorganic filler (aluminum/fluoro/silicate glass, Ketac-Fil was slightly less than that of a restorative composite material (Z100 MP).