Sulfonation of [2, 3-dichloropropyl] trifluoroethylene: synthesis of a new fluorinated β-sultone and derivatives
J Mohtasham, GL Gard, ZY Yang, DJ Burton
Index: Mohtasham, Javid; Gard, Gary L. Journal of Fluorine Chemistry, 1990 , vol. 50, # 1 p. 31 - 46
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Citation Number: 12
Abstract
Abstract Two new olefins, CH 2 BrCHBrCH 2 CF CF 2 and CH 2 ClCHClCH 2 CF CF 2, have been prepared as precursors to fluoro β-sultones. The new fluorinated sultone, CH 2 ClCHClCH 2 CFCF2OSO 2, was obtained (from the sulfonation of CH 2 ClCHClCH 2 CF CF 2), along with its rearranged isomer, CH 2 ClCHClCH 2 CF (SO 2 F) C (O) F, and hydrolysis product, CH 2 ClCHClCH 2 CF (SO 2 F) C (O) OH.
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