A relaxation-assisted 2D IR spectroscopy method.

Dmitry V Kurochkin, Sri Ram G Naraharisetty, Igor V Rubtsov

Index: Proc. Natl. Acad. Sci. U. S. A. 104(36) , 14209-14, (2007)

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Abstract

A method of two-dimensional infrared (2D IR) spectroscopy called relaxation-assisted 2D IR (RA 2DIR) is proposed that utilizes vibrational energy relaxation transport in molecules to enhance cross-peak amplitudes. This method substantially increases the range of distances accessible by 2D IR and is capable of identifying long-range connectivity patterns in molecules. RA 2DIR is illustrated in interactions among CN and CO modes in 3-cyanocoumarin and 4-acetylbenzonitrile, where the distances between the CN and CO groups are approximately 3.1 and approximately 6.5 A, respectively. A 6-fold increase in cross-peak amplitude was observed in 4-acetylbenzonitrile when the dual-frequency RA 2DIR method was used.