Carbon monoxide free aminocarbonylation of aryl and alkenyl iodides using DMF as an amide source.

Kazushi Hosoi, Kyoko Nozaki, Tamejiro Hiyama

Index: Org. Lett. 4(17) , 2849-51, (2002)

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Abstract

[reaction: see text] Palladium-catalyzed coupling reaction of N,N-dimethylformamide with aryl or alkenyl halides successfully proceeded in the presence of phosphoryl chloride to afford the corresponding tertiary amides in good yields.