Acyloxylation of 1-methoxycyclohex-1-ene and other enol ethers with dimethyl peroxydicarbonate
K Schank, H Beck, S Pistorius, T Rapold
Index: Schank; Beck; Pistorius; Rapold Synthesis, 1995 , # 8 p. 964 - 968
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Citation Number: 3
Abstract
Acyloxylation of different types of enol ethers (derived from aldehydes and ketones) by dimethyl peroxydicarbonate (DPDC) results in either addition to the double bond or in a formal replacement of an allylic hydrogen by a methoxycarbonyloxy group forming vicinal oxygenated hydrocarbons. 1, 3-Oxygenated products via monoacyloxylation could not be observed. The results are compared with copper (I)-catalyzed acyloxylations of 1- ...
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