Versatile palladium-catalyzed arylation of organomanganese chlorides by aryl bromides
E Riguet, M Alami, G Cahiez
Index: Riguet, Eric; Alami, Mouad; Cahiez, Gerard Journal of Organometallic Chemistry, 2001 , vol. 624, # 1-2 p. 376 - 379
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Abstract
In THF, a palladium-catalyzed cross-coupling reaction of organomanganese reagents with various aryl bromides including unreactive deactivated or hindered aryl bromides was performed successfully in the presence of a new catalytic system 1% PdCl2 (dppp)–four equivalents DME. The scope of the reaction is very broad since many functional groups are tolerated, moreover, even hindered O, O′-di-or trisubstituted diaryls were obtained in ...
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