Microwave-assisted aminocarbonylation of aryl bromides at low carbon monoxide pressure
F Cardullo, D Donati, G Merlo, A Paio, E Petricci…
Index: Cardullo, Francesca; Donati, Daniele; Merlo, Giancarlo; Paio, Alfredo; Petricci, Elena; Taddei, Maurizio Synlett, 2009 , # 1 p. 47 - 50
Full Text: HTML
Citation Number: 6
Abstract
Abstract An efficient and rapid procedure for microwave-assisted aminocarbonylation of aryl bromides and iodides at low CO pressure, using (PPh 3) 2 PdCl 2 or Pd (OAc) 2 as catalysts is reported. Different reaction conditions have been tested in order to carry out the reaction even on less nucleophilic anilines such as 2-chloro-4-nitroaniline, allowing a rapid access (in 20-30 min) to several diverse arylamides in good yields.
Related Articles:
[Zhang, Dong-Xue; Xiang, Shi-Kai; Hu, Hao; Tan, Wen; Feng, Chun; Wang, Bi-Qin; Zhao, Ke-Qing; Hu, Ping; Yang, Hua Tetrahedron, 2013 , vol. 69, # 47 p. 10022 - 10029]
[Li, Junmei; Xu, Fan; Zhang, Yong; Shen, Qi Journal of Organic Chemistry, 2009 , vol. 74, # 6 p. 2575 - 2577]
[Salvadori, Jessica; Balducci, Evita; Zaza, Silvia; Petricci, Elena; Taddei, Maurizio Journal of Organic Chemistry, 2010 , vol. 75, # 6 p. 1841 - 1847]
Dithiocarbamate and DBU-promoted amide bond formation under microwave condition
[Kumar, Katari Naresh; Sreeramamurthy, Kintali; Palle, Sadananda; Mukkanti, Khagga; Das, Parthasarathi Tetrahedron Letters, 2010 , vol. 51, # 6 p. 899 - 902]
[Yadav, Lal Dhar S.; Garima; Srivastava, Vishnu P. Tetrahedron Letters, 2010 , vol. 51, # 4 p. 739 - 743]